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Synthesis, characterization and hydroformylation catalytic activity of a water-soluble RhCl(CO)(PySO3Na)2 complex using 1-hexene and real naphtha
(2012-03-16)
In this work, we describe the synthesis and characterization of a new water soluble [RhCl(CO)(PySO3Na)2], complex (1); where [PySO3Na] is the
sodium salt of p-sulfonated pyridine ligand. Complex (1) was obtained in methanol, ...
Synthesis, characterization, and biphasic ionic liquid media 1-hexene hydrogenation reaction of RuCl2(DMSO)2(NC5H4CO2Na-3)2
(Publicado en Science+Business Media B.V., 2011-06)
RuCl2(DMSO)2(NC5H4CO2Na-3)2 is very soluble
in the ionic liquid (IL) 1-n-butyl-3-methylimidazolium tetrafluoroborate, [(BMIM)BF4]. The complex was prepared by
reacting RuCl2(DMSO)4 with NC5H4CO2Na-3, sodium nicotinate, in ...
Synthesis, characterization and olefin hydroformylation reactions of mer-[Mo(CO)3(p-C5H4N-CN)3]
(Springer Science+Business Media B.V. 2010, 2010-01-12)
Mer-[Mo(CO)3(p-C5H4N-CN)3] was prepared
by UV-irradiation of a THF solution of Mo(CO)6 and paracyanopyridine
under heating. The complex was characterized
by FT-IR, MS, 1H and 13C NMR and showed catalytic
activity for olefin ...
Hydroformylation reactions of the trans-Mo(CO)4(p-C5NH4SO3NA)2 complex in biphasic medium
(Akadémiai Kiadó, Budapest and Springer, Dordrecht, 2008-10-12)
Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex,
(trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1-
hexene hydroformylation reaction, in biphasic toluene/water medium ...
Synthesis and characterization of trans-Mo(CO)4(p-C5NH4SO3Na)2
(Akadémiai Kiadó, Budapest and Springer, Dordrecht, 2008-03-12)
Reaction between Mo(CO)6 and p-C5NH4SO3Na (1:2 (Mo: p-C5NH4SO3Na)
stoichiometric ratio) gave the trans-Mo(CO)4(p-C5NH4SO3Na)2 complex, (1), in
80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR
spectroscopy. ...